Benzene

    • Product Name: Benzene
    • Chemical Name (IUPAC): Benzene
    • CAS No.: 71-43-2
    • Chemical Formula: C6H6
    • Form/Physical State: Liquid
    • Factroy Site: No.1188 West 2nd Ring Road, Shengze, Wujiang, Suzhou, Jiangsu, China
    • Price Inquiry: sales2@ascent-chem.com
    • Manufacturer: Shenghong Holding Group
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    VTB
    Specifications
    HS Code 902852
    Name Benzene
    Chemical Formula C6H6
    Molar Mass 78.11 g/mol
    Appearance Colorless liquid
    Odor Sweet, aromatic
    Melting Point 5.5 °C
    Boiling Point 80.1 °C
    Density 0.8765 g/cm³
    Solubility In Water 0.18 g/100 mL (25 °C)
    Flammability Highly flammable
    Vapor Pressure 12.7 kPa (20 °C)
    Autoignition Temperature 498 °C
    Refractive Index 1.5011 (20 °C)
    Flash Point -11 °C
    Cas Number 71-43-2

    As an accredited Benzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Benzene is typically packaged in a 200-liter steel drum with hazardous material labeling, UN-approved markings, and secure, leak-proof sealing.
    Container Loading (20′ FCL) Benzene is typically loaded in a 20′ FCL using steel drums or ISO tanks, maximizing efficiency and ensuring safe transportation.
    Shipping Benzene is shipped as a hazardous chemical due to its flammability and toxicity. It must be transported in tightly sealed, properly labeled containers, often by tank trucks or railcars designed for flammable liquids, in compliance with regulations such as DOT and IMDG. Ensure safety data sheets and emergency procedures accompany the shipment.
    Storage Benzene should be stored in tightly closed, properly labeled containers in a cool, dry, well-ventilated area away from ignition sources and incompatible substances such as oxidizing agents. Storage areas must be equipped with spill containment and kept away from direct sunlight, heat, and static discharge. Use explosion-proof equipment and ensure all containers are grounded and bonded during transfer to minimize fire risk.
    Shelf Life Benzene typically has a shelf life of two years when stored properly in tightly sealed containers away from heat and direct sunlight.
    Application of Benzene

    Applications of Benzene in Industrial Manufacturing

    Benzene serves as a fundamental aromatic hydrocarbon building block critical to numerous chemical manufacturing streams. Direct feedstock integration, precise formulation, and compliance alignment drive its downstream value. Below, key industrial sectors illustrate specific application scenarios, technical processing, and end-market products derived from benzene.

    1. Production of Styrene Monomer for Polystyrene Manufacturing

    Styrene monomer production relies on ethylbenzene dehydrogenation, where benzene operates as a principle aromatic raw material for alkylation with ethylene. Strict hydrocarbon purity is essential in catalyst-driven reactors to ensure high yield and low impurity levels in monomer output, which directly feeds polymerization units for polystyrene manufacturing. Quality control addresses color, benzene residue, and byproduct minimization prior to compounding and pelletizing stages.

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    2. Synthesis of Cumene for Phenol and Acetone Pathways

    Benzene is essential in cumene synthesis through alkylation with propylene under specific temperature and pressure using solid or liquid acid catalysts. Carefully controlled injection of benzene ensures low oligomer formation and prevents feedstock waste. Cumene oxidation units utilize strict oxygen dosing and continuous phase separation to produce phenol and acetone as critical downstream intermediates for plastics, resins, and solvents.

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    3. Linear Alkylbenzene (LAB) Manufacturing for Surfactants

    Benzene undergoes catalytic alkylation with linear mono-olefins, typically from kerosene hydrocracking, to yield LAB, the primary intermediate for anionic surfactant synthesis in industrial and household detergents. LAB production demands optimized feedstock blending for carbon distribution, color stability, and minimized branching, with post-reaction hydrogenation steps ensuring compliance with surfactant biodegradability limits.

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    4. Cyclohexane Production for Nylon Intermediates

    The manufacture of cyclohexane employs liquid-phase or vapor-phase hydrogenation of benzene under pressurized hydrogen flows in the presence of nickel or noble metal catalysts. Feedstock quality influences catalyst life and hydrogen consumption. Cyclohexane serves as the essential precursor for adipic acid and caprolactam synthesis, both used in further downstream processing for engineering plastics and synthetic fibers. Plant process engineers closely monitor conversion rates, contaminants, and resultant color for textile-grade output.

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    5. Manufacture of Aniline for Polyurethane Systems

    Aniline production utilizes benzene nitration followed by catalytic hydrogenation of nitrobenzene. Plant technicians monitor nitrate dosing and exothermic control for product consistency. Subsequent purification is essential to avoid downstream catalyst poisoning in MDI synthesis for polyurethanes. Aniline is further reacted with formaldehyde and phosgene to produce hard and flexible polyurethane foams, especially in automotive, insulation, and appliance applications, where component specifications demand consistency and compliance.

    Industry compliance standards

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    6. Maleic Anhydride Production via Benzene Oxidation

    Benzene is utilized in vapor-phase catalytic oxidation processes to generate maleic anhydride, employing vanadium or molybdenum oxide-based catalysts at controlled temperatures. Advanced process control systems regulate benzene feed rates and prevent hot-spot formation in reactors. Maleic anhydride serves as a key input for resins, unsaturated polyester, and specialty chemical manufacturing. Process integration ensures minimal benzene slip and abatement for emission regulation.

    Industry compliance standards

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    Certification & Compliance
    More Introduction

    Benzene: Chemical Industry Backbone from an Experienced Manufacturer’s Perspective

    What It Takes to Produce Reliable Benzene Every Day

    Every time we switch on a reaction vessel or monitor the output lines in our benzene plant, we face a reality known only to upstream chemical manufacturers: the details matter at every stage. From the raw feedstock input to the fractionation towers to the way each batch leaves our loading bay, benzene’s journey is full of variables that keep seasoned operators on their toes. The product commonly referred to as benzene—sometimes labeled under Model BZ-998 or BZ-AR in industry communication—is not just a staple hydrocarbon. It is one of the purest building blocks for a wider range of chemicals you see every day, from styrene for plastics to cyclohexane for nylon manufacturing.

    From decades of monitoring and refining our output, I can say with confidence that achieving the right benzene purity isn’t about running the standard process chart with a watchful eye—it’s about managing heat, pressure, and, most crucially, the consistency of the feedstock. Light naphtha or reformate, which we often take from our integrated refinery, brings its own fingerprint of contaminants. Every batch can respond a little differently in the reformer and each distillation sequence. Our operators have had to learn not only what instrument readings should show but also the characteristics of an optimal liquid-phase split and a stable fractionation column. Here’s where real chemical manufacturing stands apart from blends or third-party drum refilling: what leaves our tank farm can only be called benzene after a dozen internal checks for density, color, and vapor pressure.

    Real-World Specifications: Beyond the Book Numbers

    One of the practical realities in benzene manufacturing is pressure from the market to deliver higher grades with extremely low impurity profiles. Customers don’t just want “industrial” or “lab” grade—with benzene, trace impurities like thiophene, sulfur, and water can change everything in downstream production. Many years ago, I worked shifts where we measured sulfur content to 0.5 ppm and moisture below 200ppm. Not for a data sheet, but because unwanted interactions in alkylation or chlorination can wreck yields or trigger extra by-product handling.

    Our specification grades have adapted to this. Most commonly, we supply two main models: BZ-998, a high-purity product used for organic synthesis, and BZ-AR, a grade well-suited for analytical work and polymer intermediates. BZ-998 keeps total impurities below 0.02%, a margin far tighter than what some import drums show. We draw on our in-house GC analysis, and those machines don’t lie. We also offer tailored lots for regular customers with ultra-low water (under 50 ppm) because water in benzene delays catalyst action, particularly for those running continuous reactors.

    Color sounds cosmetic, but experience has taught us otherwise. A slight yellow tinge in benzene often betrays trace unsaturates and heavy aromatics, which our fractionators must work harder to reject. Such coloration can seem trivial, but we know users in aniline or nitrobenzene synthesis see immediate process fouling if color creeps up, resulting in time-consuming cleanouts. Our practice remains—release nothing above APHA 10 for color index, because everything above that puts downstream efficiency on the line.

    On Usage: Where Benzene Earns Its Place

    Having supplied benzene to a wide span of industries, I’ve seen how customers use each grade differently. For large-volume styrene producers, the purity demands are relentless—their dehydrogenation catalysts react poorly to chlorine or sulfur. Several years ago, a key buyer reported mysterious fouling in one of their reactors. Investigation found trace CS2 picked up from a contaminated drum. After that, they insisted on our BZ-998 batches, direct from our central plant, supporting annual volumes in the tens of thousands of tons. With the right grade, equipment lifetime increases and fewer shutdowns occur.

    On the other hand, specialty labs using analytical-grade benzene appreciate clear transparency, because their spectroscopic equipment flags every minute anomaly. We’ve had universities and pharmaceutical companies request single-barrel deliveries subject to an extra layer of quality testing. As hands-on producers, we’re used to accommodating special testing—our lab chemists often run additional refractive index or gas chromatograph scans to verify that even the sub-ppm impurities match their unique syntheses.

    A lot is written about benzene’s toxicity, but those of us in charge of handling tonnage day after day recognize that safety practices aren’t just policy—they’re the backbone of responsible operations. We have invested in continuous emissions monitoring, redundant containment, and personal protection systems for our teams. Only with this kind of long-term focus can a manufacturer maintain a reputation for supplying benzene that meets regulatory and ethical standards globally.

    How Benzene Differs from Other Aromatics

    People curious about benzene often compare it directly with toluene or xylene, since they all come from the same basic aromatics stream. As a manufacturer, I see these distinctions up close. Benzene’s six-carbon, fully conjugated ring makes its chemical behavior remarkably versatile. In the production plant, it’s the most volatile of the three, with a boiling point just below 81°C. Our separation columns operate with tighter margin settings for benzene recovery, so our seasoned operators learn to spot the conditions where toluene “creep” can impact the BZ-998 grade.

    It’s easier, on the face of it, to remove impurities from toluene than benzene, especially sulfur. Toluene can be fractionated and hydrotreated to achieve similar purities, but the reactivity or downstream requirements are rarely as strict. Xylene, often sold in mixed grades or as the ortho-para separation product, brings additional handling issues and the risk of isomer redistribution during process upsets. We frequently get requests to “substitute with toluene” as a cost-saving measure for non-critical uses, but any manufacturer with experience in polystyrene, epoxy resins, or phenol production knows that the core chemistry pivots on benzene’s molecular configuration. Once, a top-tier adhesives plant attempted to run a toluene-based process modification in place of benzene. Within two weeks, viscosity swing issues and product consistency complaints led them back to our doors.

    We’re sometimes asked to comment on alternative sourcing for phenols or anilines, as downstream markets look for flexibility. Our feedback: there isn’t a direct substitute for benzene if the end-product depends on strict molecular structure. The reasons trace back to how electrophilic substitution proceeds on the benzene nucleus, something any industrial chemist has grappled with while trying to avoid off-spec isomers.

    Why Benzene Quality Shapes Industry Performance

    In the years I’ve walked the plant and sat with customers listening to problems, a pattern keeps repeating: process issues downstream almost always track back to the feedstock. High-end polycarbonate, for example, demands phenol produced via cumene route. If our benzene batch runs high on water, it holds up the entire phenol unit as the caustic wash takes longer, losing throughput daily.

    Not long ago, our technical support team worked with a major tire manufacturer. They noticed uneven curing in their styrene-butadiene rubber. The problem eventually traced back to variable methylcyclopentadiene content in the benzene delivered from a competing supplier. Our own feedstock control means our deliveries avoided the spike. Our product specs may look similar on paper to other suppliers, but the way we handle process control, loading, and logistics means that the delivered benzene performs as expected, batch after batch.

    For downstream chemists, especially those involved in dyes, agrochemicals, or pharmaceuticals, unreliable benzene quality can cause rework, delays, and extra purification expense. We act as more than “just a supplier”—over the span of a contract, our field engineers consult with our partners, offering advice on storage, transfer, and pre-processing. This real-world partnership improves not just the chemical, but the plant’s bottom line.

    Meeting Global Expectations Year after Year

    Different regions call for different certifications, and that’s not just a formality. In Europe, our shipments meet REACH compliance, not only because customers demand it but because environmental regulations enforce consequences for missing even minor thresholds of certain impurities. In North America, API and ASTM standards drive most acceptance criteria, especially for industrial manufacturers. In Asia, buyers seek detailed certificates of analysis, checked routinely by independent labs. We’re prepared to honor these with each consignment, backed up by digital records from our own test benches.

    Years ago, the assumption was that bulk buyers cared only for volume and price, but over time, buyers have prioritized origin, traceability, and batch reproducibility. Our facility stands ready for customer audits, from the raw material storehouse to each calibration in our analytical lab. We don’t consider compliance a marketing tool, but a necessary investment for keeping international partners satisfied.

    Transportation remains a key consideration. Our tanks, pumping systems, and pipelines meet double-containment protocols. Shipments go out in railcars and iso-tanks, never open drums, reducing the risk of cross-contamination and accidental release. Several clients who formerly sourced from trading houses have commented on the lower variance and improved odor profile from our direct loads. Our drivers undergo extensive hazardous material training, not because of regulations, but because our teams expect nothing less for our own safety standards.

    Supporting Sustainability and Innovation

    Manufacturers now face rising scrutiny over benzene-related emissions in both production and downstream use. Our facility has invested in vapor recovery systems, closed-loop cooling, and process water recycling. Real improvements come not from public relations, but from steady capital upgrades and boots-on-the-ground work. Years ago, we installed advanced flare minimization controls, which allowed us to reclaim fugitive benzene during upsets and maintenance—yielding both environmental and economic benefits.

    Research groups often approach us about bio-based aromatics and the potential shift in chemical feedstocks. We track these trends, but current technology rarely delivers the volumes or purity of traditional production. Even so, we work with university partners on pilot projects and alternative fractionation schemes. Over time, we believe next-generation technologies may complement, but not replace, the reliability of established benzene operations, especially where exacting purity remains non-negotiable.

    Waste management forms a cornerstone of our production chain. We ensure that spent catalysts and off-gas condensates are neutralized and contained before disposal or regeneration. Our workers attend compulsory environmental and health training—because even experienced hands can benefit from updates. As a result, incidents involving leaks or releases have dropped sharply over the past decade.

    Working Hand-in-Hand with Industry Partners

    No manufacturer delivers in a vacuum. In our decades of operation, we’ve learned that honesty about production challenges builds lasting trust. During rare supply interruptions, we communicate with buyers early, offering alternative logistics or shifting production windows to match downstream shutdowns. Recurring customers come not merely for the price, but the confidence that comes with every truck or tank load.

    We also serve as an information resource, regularly advising buyers in adjacent industries about regulatory changes, safe handling practices, or innovations in process engineering. Our technical specialists travel onsite to troubleshoot, not only for our benefit but because a stronger partner is a better customer. Wherever changes in benzene regulations set new limits for storage or transport, we share our own best practices and paperwork, streamlining compliance for all sides involved.

    Looking Ahead: Why Benzene Will Remain Core to Chemical Manufacturing

    Chemicals like benzene shape the economy more deeply than most other products. Polystyrene, phenol, nylon, pigments—all start with benzene as a core ingredient. Even as the world talks about renewable resources and green chemistry, the demand for ultra-pure benzene remains steady. Our experience suggests that as new applications arise in electronics, pharmaceuticals, and advanced polymers, there will be rising expectations for traceability, tighter impurity control, and sustainable processing in benzene production.

    We commit ourselves each day to keeping up with these changes. By working closely with engineers, running constant R&D, and holding true to our process control standards, we aim to deliver benzene that enables progress across the manufacturing world. The details may seem small—a touch less sulfur, a shade less water, a slightly tighter boiling point range—but these things make all the difference for our customers and for the industries that depend on us.